Addition of a Chiral Copper Reagent Derived from Propargylic Oxazolidininone to Aldehydes

Nacira Alouane; Frederic Bernaud; Jerôme Marrot; Emmanuel Vrancken; Pierre Mangeney

doi:10.1021/ol0522743

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Addition of a Chiral Copper Reagent Derived from Propargylic Oxazolidininone to Aldehydes

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Addition of a Chiral Copper Reagent Derived from Propargylic Oxazolidininone to Aldehydes

Nacira Alouane, Frederic Bernaud, Jerôme Marrot, Emmanuel Vrancken et Pierre Mangeney

Organic letters, Vol.7(26), pp.5797-5800

22/12/2005

DOI: https://doi.org/10.1021/ol0522743

PMID: 16354069

Résumé

Chemical Sciences

Organic chemistry

The copper reagent arising from an optically pure propargylic oxazolidinone was found to react regio- and diastereoselectively with aldehydes, leading, in a one-pot procedure, to the anti homopropargylic amino alcohols derivatives in good yields.

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Détails

Titre: Addition of a Chiral Copper Reagent Derived from Propargylic Oxazolidininone to Aldehydes
Créateurs - sans rôle: Nacira Alouane - Chimie Organique
Frederic Bernaud - Chimie Organique
Jerôme Marrot - Synthèse, interactions et réactivité en chimie organique et bioorganique
Emmanuel Vrancken - Chimie Organique
Pierre Mangeney - Chimie Organique
Détails de publication: Organic letters, Vol.7(26), pp.5797-5800
Éditeur: American Chemical Society
Nombre de pages: 4
Identifiants: 99138932109311
Unité académique: Institut Charles Gerhardt Montpellier - ICGM
Langue: English
Type de ressource: Journal article