Abstract
Homoleptic and cationic [Ag(IPr)2]PF6 [IPr = 1,3‐bis(2,6‐diisopropylphenyl)imidazolylidene] is an efficient catalyst for the A3‐coupling reaction. Propargylamines are synthesized in short reaction times with low catalyst loadings under microwave irradiation or continuous flow. This approach is user friendly, versatile, and compatible with both aliphatic and aromatic aldehydes and alkynes.