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A bicyclic unit reversal to stabilize the 12/14-helix in mixed homochiral oligoureas
Article de revue   Open Access   Avec comité de lecture

A bicyclic unit reversal to stabilize the 12/14-helix in mixed homochiral oligoureas

Pierre Milbeo, Matthieu Simon, Claude Didierjean, Emmanuel Wenger, Emmanuel Aubert, Jean Martinez, Muriel Amblard, Monique Calmès et Baptiste Legrand
Chemical Communications, Vol.56(57), pp.7921-7924
17/07/2020
DOI: https://doi.org/10.1039/d0cc02902e

Résumé

The insertion of cyclic building blocks in oligoureas to stabilize or modulate the properties of the 12/14-helix was often fruitless. We herein propose a fully compatible highly constrained building block that could be incorporated into oligoureas to develop highly stable and functionnal oligoureas helices.

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