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[3]Foldarotaxane-mediated synthesis of an improbable [2]rotaxane
Journal article   Open access   Peer reviewed

[3]Foldarotaxane-mediated synthesis of an improbable [2]rotaxane

Victor Koehler, Maxime Gauthier, Chenhao Yao, Karine Fournel-Marotte, Philip Waelès, Brice Kauffmann, Ivan Huc, Frédéric Coutrot and Yann Ferrand
Chemical Communications, Vol.58(62), pp.8618-8621
02/08/2022
PMID: 35786713

Abstract

The wrapping of a helix around the axle of a [2]rotaxane induced compartmentalization by sequestrating the macrocycle around a part of the axle for which it has no affinity. It gave this way the opportunity to yield an improbable [2]rotaxane.
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