Résumé
CO2 sequestration in deep geological formation is considered an option to reduce CO2 emissions in the atmosphere. After injection the CO2 will slowly dissolve into the pore water producing low pH fluids with a high capacity for dissolving carbonates. Limestone rock dissolution induces geometrical parameters changes such as porosity, pore size distribution, or tortuosity which may consequently modify transport properties (permeability, diffusion coefficient). Characterizing these changes is essential for modelling flow and CO2 transport during and after the CO2 injection. Indeed, these changes can affect the storage capacity and injectivity of the formation. Very few published studies evaluate the transport properties changes (porosity, permeability, pore size distribution, diffusion coefficient) due to fluid-rock interactions. Here we report experimental results from the injection of acidic fluids (some of them equilibrated with gypsum) into limestone core samples of 25.4 mm diameter and around 25 mm length. Experiments were realized at room temperature. Before and after each acidic rock attack, we measure the sample porosity, the diffusion coefficient and the pore size distribution. We also image the 3D pore network by X ray microtomography. During percolation experiments, the permeability changes are recorded and chemical samples taken to evaluate calcite dissolution. Several dissolution-characterization cycles are performed on each sample in order to study the evolution and relation of the different parameters. These experiments show different dissolution regimes depending of the fluid acidity and of the limestone sample. Wormhole formation is the dominant dissolution regime. Nevertheless, the wormhole structure changes depending of the initial rock properties.