Résumé
Numerous artificial transport systems utilizing carriers, channel-forming or self-organized polymeric superstructures able to orient, to select and to pump the ionic transport across membranes have been developed in the last decades. Of special interest is the structure-directed function of hybrid membrane materials and control of their build-up from suitable units by self-organisation. The main interest focus on functional hybrid membrane materials in which the recognition-driven transport properties or the creation of directional transporting pathways could be ensured by a well-defined incorporation of receptors of specific molecular recognition and self-organization functions. We are therefore proposing to review the membrane transport properties of such supramolecular hybrid materials with potential in renewable energy applications as fuell-cells technology, biomimetic water and ion channels, etc. [1] M. Barboiu, C. Luca, C. Guizard, N. Hovnanian, L. Cot, G. Popescu, J. Membrane Sci., 1997, 129, 197-207. [2] M. Barboiu, C. Guizard, J. Palmeri, C. Reibel, C. Luca, L. Cot, J. Membrane Sci. 2000, 172, 91-103. [3] M. Barboiu, S. Cerneaux, G. Vaughan, A. van der Lee, J. Am. Chem. Soc. 2004, 126 3545-3550. [4] A. Cazacu, C. Tong, A. van der Lee, T.M. Fyles, M. Barboiu, J. Am. Chem. Soc. 2006, 128(29), 9541-9548. [5] C. Arnal-Herault, A. Pasc-Banu, M. Barboiu A. van der Lee, Angew. Chem. Int. Ed. 2007, 46, 4268-4272. [6] C. Arnal-Herault, A. Pasc-Banu, M. Michau, M. Barboiu, Angew. Chem. Int. Ed. 2007, 46, 8409-8413. [7] C. Arnal-Hérault, M. Barboiu, A. Pasc, M. Michau, P. Perriat, A. van der Lee, Chem. Eur. J. 2007, 13, 6792 [8] M. Michau, M. Barboiu, R. Caraballo, C. Arnal-Hérault, A. van der Lee, Chem. Eur. J. 2008, 14, 1776-1783. [9] M. Barboiu, P. Aimar, J.M. Lehn, From simple molecules to complex membrane systems, Editorial, Special issue of J. Memb. Sci., 2008, 321, 1-2. [10] M. Michau, M. Barboiu, J. Mater. Chem., 2009, 19, 6124-6131. [11] A. Cazacu, Y.M. Legrand, A. Pasc, G. Nasr, A. van der Lee, E. Mahon, M. Barboiu, Proc. Natl. Acad. Sci., 2009, 106(20), 8117-8122. [12] S. Mihai, A. Cazacu, C.Arnal-Herault, G. Nasr, A. Meffre, A. van der Lee, M. Barboiu, New. J. Chem, 2009, 33, 2335-2343. [13] M. Barboiu, Chem. Commun. 2010, 46, 7466-7476. [14] Y. Le Duc, M. Michau, A. Gilles, Valerie Gence, Y.-M. Legrand, A. van der Lee, S. Tingry, M. Barboiu,; Angew. Chem. Int. Ed. 2011, DOI : 10.1002.anie.201103312